Star Exclusive: They Did It! Brad & Angelina Tie The Knot!

Star can exclusively reveal that Brad Pitt and Angelina Jolie, who are expecting twins this summer, tied the knot during an intimate wedding ceremony in the couple's adopted city of New Orleans, Louisiana on Saturday afternoon.

As Star has reported, Brad had long wanted the ceremony to take place in the city devastated by Hurricane Katrina, while Angelina preferred a small, intimate ceremony in France. Clearly Brad won out as the planned ceremony took place in the French Quarter Wedding Chapel. The now husband and wife, along with their four children, are expected to return to Texas, where Brad is currently filming Tree of Life.

This is the second trip down the aisle for Brad, who ended his five-year marriage to Jennifer Aniston shortly after meeting Angelina on the set of their 2005 film Mr. & Mrs. Smith. Twice-married Angelina divorced actors Jonny Lee Miller in 1999 and Billy Bob Thornton in 2003 after three-year marriages to each.

For all the inside wedding details, check out the new issue of Star, on sale starting Wednesday!